Counter ions might be included. Small deviations from ideal geometry may be due to crystal packing. See original references for the crystal structure.

Metal Alkene ComplexesDOICCDC code
A
Ni(CH2=CH2)2(C7H13N)
doi.org/10.1002/anie.198907721SAXSOZ 1255691
Ni(CH2=CH2)(PPh3)2 doi.org/10.1107/S0567740881004640TPPENI11 1275450
Ni(CH2=CH2)(PPh3)(PMe2CH2CH2PMe2) Zeitschrift fur Naturforschung,
B:Chemical Sciences (1984) 39, 1076
COFVIC 1128627
Mn(CH2=CH2)H(PMe2CH2CH2PMe2)2 doi.org/10.1021/acs.organomet.8b00379XILJOU 1846647
B
Os(CH2=CH2)(CO)4
doi.org/10.1021/om00046a049YAHZEM 1298872
Fe(CH2=CH2)(CO)3(PPh3) doi.org/10.1002/cber.19851181005CUBDOS10 1132099 with added H
Fe(CH2=CH2)2(PiPr2CH2CH2CH2PiPr2) doi.org/10.1002/anie.201410069NOSVIC 1026194
Os(CH2=CH2)H2(NO)(PiPr3)2PF6 doi.org/10.1021/om000901gXIKHAA 1296626
C
cis-Ir(CH2=CH2)2Cl2
doi.org/10.1021/acs.organomet.1c00250IZAQOS 2064402
cis-Rh(CH2=CH2)2Cl2 doi.org/10.1021/jacs.0c05286TUWSAI 2003252
Rh(CH2=CH2)2(acac) doi.org/10.1021/om000419yACDERH01 158474
Co(CH2=CH2)(PMe3)3(MeCN)+ doi.org/10.1021/ja00378a018ACNCOC10 1100828
Rh(tBuCH2)(CH2=CH2)(PtBu2CH2PtBu2) doi.org/10.1021/om100413mIMENIY 775509
D
Ir(CH2=CH2)2Cl(PEt3)2
doi.org/10.1021/om960385nTORNAP 1274270 without disorder
Ir(CH2=CH2)3(PPh3)2+ doi.org/10.1021/om034177oAROPOM 231452
Ir((NC)2C=C(CN)2)(PPh3)2(CO)(OMe) doi.org/10.1016/0022-328X(87)80373-XFEZVEL 1155618
Rh(tBuCH2)(CH2=CH2)(PtBu2CH2PtBu2) doi.org/10.1021/om100413mIMENIY 775509
E
KPt(CH2=CH2)Cl3
doi.org/10.1021/ic50153a012KCLEPT03 1193860
Pt(CH2=CH2)(PCy3)2 doi.org/10.1016/S0277-5387(00)80384-8VAZZOL 1280955
Pt(CH2=CH2)2(CF2=CF2) doi.org/10.1098/rspa.1983.0029ETFEPT11 1150464
Pt2(CH2=CH2)2Cl4 doi.org/10.1107/S1600536807059636HIQRAB 672721
F
W(CH2=CH2)(CO)5
doi.org/10.1016/j.inoche.2005.10.025REDNUK 284305
W(CH2=CH2)(CO)3(PCy3)2 doi.org/10.1021/ic960870aREZGUY 1249201
Mo(CH2=CH2)2(PMe3)4 doi.org/10.1021/ja00348a014BIFJOP10 1110449 with modified H
Rh(CH2=CH2)2(C4H8O)2PF6 doi.org/10.5517/ccdc.csd.cc230xtwTONQIZ 1937308
G
cis-Pt(CH2=CH2)2Cl2
doi.org/10.1016/j.inoche.2006.04.006BOFTEV11 293062
Au(CH2=CH2)3(SbF6) doi.org/10.1002/anie.200703515KISVOY 656269
Rh(CH2=CH2)(PiPr3)2Cl doi.org/10.5517/ccpx7g8EIPPRH01 652750
Rh(CH2=CH2)2(PCy2CH2CH2PCy2)+doi.org/10.1039/C7SC01491KXAZMUJ 539833
H
W(CH2=CH2)2(CO)4
doi.org/10.1039/a808621dFERDIP 120630
W(CH2=CH2)4H-3 doi.org/10.1021/om9901527WOKYEA 1294529
Ru(CH2=CH2)(PMe3)4 doi.org/10.1016/S0277-5387(00)84672-0DEBWOW 1137700
Fe(CH2=CH2)2(PPh2CH2CH2PPh2)2doi.org/10.1021/acs.organomet.6b00803FAPKOZ 1510841
I
Ni(MeC≡CMe)(PiPr2CH2CH2PiPr2)
doi.org/10.1021/om990387iXECSUT 1295737
Re(PhC≡CPh)(PEt3)2(CO)(NO) doi.org/10.1002/hlca.19930760219WEDNEY 1291230
Mo(HC≡CH)(PPh2CH2CH2PPh2)2 doi.org/10.1021/om0007623QOHQUZ 160173
Os(HC≡CH)(CH2=CH2)(en)2Cl2 doi.org/10.1021/ja00059a080YAMYAM 1299274
J
Ni(PhC≡CPh)bipy
European Journal of Inorganic Chemistry (2001) 77QEYFUV 144795 with added H
Cu(HC≡CH)bipyClO4 doi.org/10.1039/dt9920002225YAFSON 1298628
W(HC≡CH)Br2(PPh3)2(CO) doi.org/10.5517/ccdc.csd.cc278v9pAMOVEG 2064082
Ru(PhC≡CPh)(PEt3)2(CO)2 doi.org/10.1021/om9700775NAKJIS 1216284
K
W(HC≡CH)(MeCN)2(CO)Br2
doi.org/10.1002/chem.201903264WUDHAH 1918484
W(HC≡CH)2(MeCN)(CO)Br2 doi.org/10.1002/chem.201903264WUDGUA 1918483
Ni(HC≡CH)(PPh3)2 doi.org/10.1002/anie.198503231DANLAF 1136129
Pt(PhC≡CPh)(PPh2CH2CH2PPh2)doi.org/10.1039/c0nj00118jPUXSUX 765288
L
Co2(tBu-C≡C-tBu)(CO)6
doi.org/10.1021/ic00231a024BACCCO02 1104620
W2(HC≡CH)(py)2(OiPr)6 doi.org/10.1021/ja00334a055BUDBOR10 1115962
Re(CH2=CH2)(NO)Cl2(PiPr3)2 doi.org/10.5517/cc9zvcgGOFYOQ 297766
Re(CH2=CH2)(CH2=CHCH=CH2)(PPh3) doi.org/10.1021/om201187wBEKWOF 854185
M
V(CH2CHCH2)(CO)4(PPh3)
doi.org/10.1016/S0022-328X(00)80767-6ALCPPV 1102206 with added H
Co(CH2CHCH2)(CO)2(PPh3) doi.org/10.1002/cber.19791120607ALDCCO 1102215 with modified H
Ni(CH2CHCH2)(CH2CH2CH2CH2) doi.org/10.1021/om030448jALEMIN 222566
Ni(CN)(CH2CHCH2)(PiPr2CH2CH2PiPr2) doi.org/10.1016/S0022-328X(03)00431-5ILUYUJ 207395
N
Fe(CH2CHCH2)(CO)3Br
doi.org/10.1021/ic50210a031ALCFEA 1102192 with modified H
Ru(CH2CHCH2)(NO)(PPh3)2 doi.org/10.1021/ic50189a017ALLNPR10 1102267 with modified H
Fe(CH2CHCH2)(NO)(PPh3)(CO) doi.org/10.1246/bcsj.71.403POQPIU 1236996
Ru(CH2CHCH2)(H2O)(CO)3(CF3SO3) doi.org/10.1021/om00004a055YUSSUA 1307382
O
Rh2(CH2CHCH2)4Cl2
doi.org/10.1021/om00050a062ALYLRH01 1102408
Ir(CH2CHCH2)(PPh3)2(CO) doi.org/10.1039/b404547eBICXOB 235531
Co(CH2CHCH2)(PPh2CH2CH2PPh2)(CO) doi.org/10.1039/b815853cYOWBOC 701811
Mo(CH2CHCH2)(bipy)(C≡CPh)(CO)2 doi.org/10.1021/om0107800MITQUB 185276
P
Mo(CH2CHCH2)(bipy)Br(CO)2
doi.org/10.1016/S0022-328X(01)00988-3ICOPEV 159348
Mo(CH2CHCH2)(bipy)Me(CO)2 doi.org/10.1021/ja015538zEFIJAE 1148965 without disorder
Mo(CH2CHCH2)(en)Br(CO)2 doi.org/10.1016/j.jorganchem.2009.10.031BUKHOF 732782
Mo(CH2CHCH2)(en)(CN)(CO)2 doi.org/10.1016/j.jorganchem.2009.10.031BUKJOH 732787
Q
Ni(CH2CHCH2)(PMe3)3PF6
doi.org/10.1021/om0601807NEHCOT 609124
Ni(CH2CHCH2)2(PPh3) doi.org/10.1016/S0022-328X(00)81073-6ALPHNI 1102347
Cr(CH2CHCH2)2(PiPr2CH2CH2PiPr2) doi.org/10.1021/om00056a022JODWOO 1188109
Mo(CH2CHCH2)(MeCN)3(CO)2BF4 doi.org/10.1021/om2010244XESWID 849579
R
Ni(CH2CHCH2)2
doi.org/10.1021/om00121a014BIPJEP 1111382
Ni(CH2CHCH2)(PPh3)2BF4 doi.org/10.1021/om050285uLASFAN 281420
Pd(CH2CHCH2)(py)Cl doi.org/10.1002/ejic.201001300UVOXUZ 790288
Pd(CH2CHCH2)(PPh3)Cl doi.org/10.5517/cc3dn04ALPHPD01 101525
Cp = η5-C5H5, Cp* = η5-C5(CH3)5, py = C5H5N, Ph = -C6H5, Cy = -C6H11, Me = -CH3, Et = -CH2CH3,
iPr = -CH(CH3)2, tBu = -C(CH3)3, en = NH2CH2CH2NH2, acac = CH3COCHCOCH3

This page created by George Lisensky, Beloit College. Last modified February 16, 2023.

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