Using the index of refraction, n, with Bragg's Law, λp = 2 navg d sin(θ), and
the relationship between the radius of close-packed spheres and the layer spacing, d = r = 1.633 r,
and θ=90° for the absorbance measurement yields
λp = 1.633 Ds [ns2 f + nv2 (1-f)]1/2
λp = 658 nm (the
wavelength at peak absorbance)
ns = 1.49 (the index of refraction for the PMMA spheres)
nv = 1.00 (the index of refraction for the void air spaces)
f = 0.76 (the filling fraction for a close packed structure)
Ds = 290 nm (the diameter of the close packed spheres)