How Much are Ozone Depleting Gas Concentrations Changing?
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  1. Is there a seasonal variation? Is the concentration higher in summer or in winter? What biological processes might account for the seasonal differences?
  2. Is the northern hemisphere concentration the same as the southern hemisphere? Do gases with longer atmospheric lifetimes have smaller hemispheric differences?
  3. What is the concentration and how quickly is it changing?
  4. How does the concentration change during your lifetime compare with the seasonal variation?
  5. What would you predict for the concentration in 2100?
  6. Which gases should we worry about most?
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Concentration Units*
Click image for graphs
Ozone Depleting Potential**
Atmospheric lifetime (years)**
Carbon dioxide
CO2
link
link
ppm
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long term
0
300-1000***
Methane
CH4
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link
ppb
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long term
0
11.8
Nitrous oxide
N2O
link
link
ppb
link
long term
0.017
109
Ozone
O3
link
link
ppb
link
Total column (Dobson)
hours-days
Hydrogen
H2
link
link
ppb
0
1-2
Carbon monoxide
CO
link
link
ppb
0
0.25
Trichlorofluoromethane
CCl3F
CFC-11
link
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ppt
1
52
Dichlorodifluoromethane
CCl2F2
CFC-12
link
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ppt
0.73-0.81
102
Trichlorotrifluoroethane
CCl2FCClF2
CFC-113
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link
ppt
0.86
93
Carbon tetrachloride
CCl4
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ppt
0.89
32
Chloroform
CHCl3
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ppt
0.01
0.501
Dichloromethane
CH2Cl2
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ppt
0.004
0.493
Difluoromethane
CH2F2
HFC-32
Component (50%) of R-410A
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ppt
0
5.4
Methyl chloride
CH3Cl
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ppt
0.015
0.9
Tetrachloroethene
Cl2C=CCl2
Perchloroethylene (perc)
link
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ppt
0.007
0.301
Methyl chloroform
CH3CCl3
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link
ppt
0.14-0.17
5
Chlorodifluoromethane
CHClF2
HCFC-22
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link
ppt
0.024-0.034
11.9
Chlorodifluoroethane
CH3CClF2
HCFC-142b
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ppt
0.023-0.057
18
Dichlorofluoroethane
CH3CFCl2
HCFC-141b
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ppt
0.069-0.102
9.4
Difluoroethane
CH3CHF2
HFC-152a
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ppt
0
1.6
Tetrafluoroethane
CH2FCF3
HFC-134a
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ppt
0
14
1,1,1-Trifluoroethane
CH3CF3
HFC-143a
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ppt
0
51
Pentafluoroethane
CHF2CF3
HFC-125
Component (50%) of R-410A
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ppt
0
30
2,3,3,3-Tetrafluoropropene
CF3CF=CH2
HFO-1234yf
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<1 ppt
(decomposes to
CF3COOH)
0
0.033
Propane
CH3CH2CH3
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ppt
0
0.036
1,1,1,2,3,3,3-
Heptafluoropropane
CF3CFHCF3
HFC-227ea
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ppt
0
36
Perfluoropropane
CF3CF2CF3
PFC-218
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ppt
0
2600
Perfluorocyclobutane
C4F8
PFC-318
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link
ppt
0
3200
1,1,1,3,3-Pentafluorobutane
CF3CH2CF2CH3
HFC-365mfc
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ppt
0
8.9
Fluoroform
CHF3
HFC-23
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ppt
0
228
Perfluoroethane
CF3CF3
PFC-116
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ppt
0
10,000
Bromochlorodifluoromethane
CBrClF2
Halon-1211
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ppt
6.9-7.7
16
Methylbromide
CH3Br
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ppt
0.66
0.8
Dibromotetrafluoroethane
CBrF2CBrF2
Halon-2402
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ppt
15.7
28
Bromotrifluoromethane
CBrF3
Halon-1301
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ppt
15.2-19.0
72
Sulfur hexafluoride
SF6
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ppt
0
1,000
Trifluoromethyl sulfur pentafluoride
CF3SF5
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ppt
0
800
Nitrogen trifluoride
NF3
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ppt
0
569
Carbon tetrafluoride
CF4
PFC-14
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link
ppt
0
50,000
ppm = parts per million (106), ppb = parts per billion (109), ppt = parts per trillion (1012), ppq = parts per quadrillion (1015).

Information about Sampling Sites.

*Concentration data from the Scripps CO2 Program, the Advanced Global Atmospheric Gases Experiment (NASA and the MIT Center for Global Change Science), Global Greenhouse Gas Reference Network and Long-term global trends of atmospheric trace gases (Global Monitoring Laboratory, U. S. National Oceanic and Atmospheric Administration), Cape Grim Australia Greenhouse Gas Data (CSIRO), and the World Data Centre for Greenhouse Gases (Japan Meteorological Agency and the World Meteorological Organization).

**The Ozone Depletion Potential (ODP) is used to contrast different gases and provides a simple measure of the expected impact on ozone per unit mass emission of a gas relative to that caused by CFC-11 defined as 1. Atmospheric lifetime is used to characterize the decay of an instanenous pulse input to the atmosphere, and represents the time the input would take to decay to 0.368 (1/e) of its original value. ODP values from World Meteorological Organization, Scientific Assessment of Ozone Depletion: 2018, Table A-1 and United States Environmental Protection Agency, Ozone-Depleting Substances. Atmospheric lifetimes taken from Intergovernmental Panel on Climate Change, Climate Change 2021: The Physical Science Basis, Table 7.SM.6, p. 16-27.

***IPCC no longer lists a value for the carbon dioxide lifetime. It depends on the biosphere and concentration-dependent equilibria between the atmosphere, the ocean, and deposition of CaCO3 on timescales of a few centuries. See Annu. Rev. Earth Planet. Sci. 37:117-34 (2009) and The Atmosphere: Getting a Handle on Carbon Dioxide (NASA 2019).

Earlier versions of these pages were supported by the National Science Foundation grants DUE-9455918 and DUE-9455924.
This page created by George Lisensky, Beloit College. Last modified August 12, 2024.

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